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Angular Momentum

Angular momentum in quantum mechanics is quantized — both spin and orbital angular momentum are built from the same algebra.

Spin 1/2 particles

Sz=ℏ2(100−1)S_z = \frac{\hbar}{2} \begin{pmatrix} 1 & 0 \\ 0 & -1 \end{pmatrix}
Sy=ℏ2(0−ii0)S_y = \frac{\hbar}{2}\begin{pmatrix} 0 & -i \\ i & 0 \end{pmatrix}
Sx=ℏ2(0110)S_x = \frac{\hbar}{2} \begin{pmatrix} 0 & 1 \\ 1 & 0 \end{pmatrix}

Spin angular momentum

Content coming soon.

Orbital angular momentum

Content coming soon.

Clebsch-Gordan Tables

The j1=1/2, j2=1/2j_1 = 1/2,\ j_2 = 1/2 Clebsch-Gordan Coefficients
m1m_1m2m_2+1/2+1/2−1/2-1/2UncoupledCoupled
+1/2+1/2+1/2+1/21100∣1/2,1/2⟩∣1/2,1/2⟩\ket{1/2, 1/2}\ket{1/2, 1/2}∣1,1⟩\ket{1, 1}
+1/2+1/2−1/2-1/21/2\sqrt{1/2}1/2\sqrt{1/2}∣1/2,1/2⟩∣1/2,−1/2⟩\ket{1/2, 1/2}\ket{1/2, -1/2}∣1,0⟩\ket{1, 0}
−1/2-1/2+1/2+1/21/2\sqrt{1/2}−1/2-\sqrt{1/2}∣1/2,−1/2⟩∣1/2,1/2⟩\ket{1/2, -1/2}\ket{1/2, 1/2}∣0,0⟩\ket{0, 0}
−1/2-1/2−1/2-1/20011∣1/2,−1/2⟩∣1/2,−1/2⟩\ket{1/2, -1/2}\ket{1/2, -1/2}∣1,−1⟩\ket{1, -1}

The energy eigenvalues of the Hydrogen atom are given by

En=−12n2(Ze24πϵ0)2μℏ2n=1,2,3,...E_n = - \frac{1}{2n^2} \Bigg(\frac{Ze^2}{4 \pi \epsilon_0}\Bigg)^2 \frac{\mu}{\hbar^2} \quad n = 1, 2, 3, ...
Practice

Exercises

7 problems
1 of 7

Use the angular momentum cone model to find |L| for ℓ = 3 in units of ℏ.

The cone model shows L precessing around the z-axis for ℓ = 3. The vector magnitude |L| = √(ℓ(ℓ+1)) ℏ is shown. Enter |L| in units of ℏ.

ℓ = |L| = √12 ℏ ≈ 3.4641 ℏ
|L| = ℏ
2 of 7

For ℓ = 2, count the distinct quantized values of Lz shown in the diagram. How many are there?

The diagram shows all quantized Lz states for a given ℓ. Click each level to count them. For ℓ = 2, how many distinct mℓ values are there?

ℓ = 5 levels (2ℓ+1 = 5)
Count =
3 of 7

Find the magnitude of the electron spin angular momentum |S| in units of ℏ.

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4 of 7

Two electrons have s₁=1/2 and s₂=1/2. What are the possible values of total spin S?

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5 of 7

An electron in hydrogen has ℓ=1 and mℓ=1. Find Lz in units of ℏ.

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6 of 7

For j=3/2, find |J| in units of ℏ.

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7 of 7

Combine ℓ=1 and s=1/2. What are the possible values of j?

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Key Takeaways

  • Spin-1/2 operators are represented by the Pauli matrices (times ℏ/2)
  • Angular momentum magnitude is quantized: |L| = √(ℓ(ℓ+1))ℏ
  • Clebsch-Gordan coefficients tell you how to combine two angular momenta into a total j
  • Hydrogen's energy eigenvalues follow directly from the Coulomb central potential